Ultrasonic Nano-Structuring to Produce Porous Metals
Sonochemistry is a very effective tool for the engineering and functionalization of nano materials. In metallurgy, the ultrasonic irradiation promotes the formation of porous metals. The research group of Dr. Daria Andreeva developed an effective and cost-efficient ultrasound-assisted procedure to produce mesoporous metals.
Porous metals attract high interest of manifold technological branches due to their outstanding characteristics such as their corrosion resistance, mechanical strength and the capability to withstand exceedingly high temperatures. These properties are based on the nanostructured surfaces with pores measuring only a few nanometres in diameter. Mesoporous materials are characterized by pose sizes between 2 to 50 nm, whilst microporous material have a pore size less than 2nm. An international research team including Dr. Daria Andreeva of Bayreuth University (Department of Physical Chemistry II) has successfully developed a heavy-duty and cost-efficient ultrasound procedure for the design and production of such metallic structures.
In this process, metals are treated in an aqueous solution in such a way that cavities of a few nanometres evolve, in precisely defined gaps. For these tailor-made structures, there is already a broad spectrum of innovative applications, including air cleaning, energy storage or medical technology. Particularly promising is the use of porous metals in nanocomposites. These are a new class of composite materials, in which a very fine matrix structure is filled with particles ranging in size up to 20 nanometres.
The scheme above shows the effects of acoustic cavitation on modification of metal particles. Metals with a low melting point (MP) as zinc (Zn) are completely oxidized; metals with a high melting point like nickel (Ni) and titanium (Ti) exhibit surface modification under sonication. Aluminium (Al) and magnesium (Mg) form mesoporous structures. Nobel metals are resistant to ultrasound irradiation due to their stability against oxidation. The melting points of the metals are specified in degrees Kelvin (K).
The picture above shows that ultrasound can also be used for the protection of aluminium alloys against corrosion. On the left: The photo of an aluminium alloy in a highly corrosive solution, below an electomicroscopic image of the surface, on which – due to sonication – a polyelectolyte coating has been formed. This coating offers a protection against corrosion for 21 days. On the right: The same aluminium alloy without having been exposed to sonication. The surface is completely corroded.
The fact that different metals react in dramatically different ways to sonication can be exploited for innovations in materials science. Alloys can be converted in such a way to nanocomposites in which particles of the more stable material are encased in a porous matrix of the less stable metal. Very large surface areas thus arise in very limited space, which allow these nanocomposites to be used as catalysts. They effect particularly fast and efficient chemical reactions.
Together with Dr. Daria Andreeva, the researchers Prof. Dr. Andreas Fery, Dr. Nicolas Pazos-Perez and Jana Schäferhans, also of the department of Physical Chemistry II, contributed to the research results. With their colleagues at the Max Planck Institute of Colloids and Interfaces in Golm, the Helmholtz-Zentrum Berlin für Materialien und Energie GmbH and the Belarusian State University in Minsk, they have published their latest results online in the journal “Nanoscale”.
- Skorb, Ekaterina V.; Fix, Dimitri; Shchukin, Dmitry G.; Möhwald, Helmuth; Sviridov, Dmitry V.; Mousa, Rami; Wanderka, Nelia; Schäferhans, Jana; Pazos-Perez, Nicolas ; Fery, Andreas; Andreeva, Daria V. (2011): Sonochemical formation of metal sponges. Nanoscale – Advance first 3/3, 2011. 985-993.
- Wißler, Christian (2011): Highly precise nanostructuring using ultrasound: new procedure to produce porous metals. Blick in die Forschung. Mitteilungen der Universität Bayreuth 05, 2011.
For further scientific information, please contact: Dr. Daria Andreeva, Department of Physical Chemistry II Bayreuth University, 95440 Bayreuth, Germany – phone: +49 (0) 921 / 55-2750
Facts Worth Knowing
Ultrasonic tissue homogenizers are often referred to as probe sonicator, sonic lyser, ultrasound disruptor, ultrasonic grinder, sono-ruptor, sonifier, sonic dismembrator, cell disrupter, ultrasonic disperser or dissolver. The different terms result from the various applications that can be fulfilled by sonication.