Ultrasonic Reactors for Biodiesel Production

Ultrasonic reactors improve chemical reaction kinetics of the biodiesel conversion process. This leads to a faster transesterification, higher conversion yield, and it saves excess methanol and catalyst. Hielscher makes ultrasonic mixing reactors for the production of biodiesel at any scale. The ultrasonic reactors are compact, easy to install and very efficient.

Biodiesel Production Increased and Accelerated with Power Ultrasound

Biodiesel is a renewable and clean-burning fuel made from vegetable oils, animal fats, or waste cooking oil. It can be produced through a transesterification reaction, which involves the conversion of triglycerides into fatty acid methyl esters (FAMEs) using an alcohol and a catalyst. One way to accelerate the transesterification reaction is to use ultrasonic waves, which can enhance the mixing and mass transfer of the reactants, as well as promote the breakage of the oil droplets and the dispersion of the catalyst.
A probe-type ultrasonicator, also known as a sonotrode, is a device that generates high-frequency sound waves (typically in the range of 20 kHz to 30 kHz) by vibrating a titanium rod. The ultrasonic waves propagate through the liquid and create high-pressure and low-pressure zones, causing cavitation bubbles to form and collapse rapidly. The collapse of the bubbles generates intense local heating and cooling, high shear forces, and shock waves, which can increase the reaction rate and efficiency of the transesterification process.

Advantages of Ultrasonic Biodiesel Production

The advantages of using a probe-type ultrasonicator for biodiesel synthesis include:

1. Faster reaction rate: The ultrasonic waves can increase the mass transfer of the reactants and accelerate the transesterification reaction, reducing the reaction time and increasing the yield of biodiesel.
2. Higher yield and purity: The ultrasonic biodiesel process improves the dispersion of the catalyst and the homogeneity of the reaction mixture, leading to a higher yield and purity of biodiesel. Using ultrasonics, you can use lowest feedstock quality such as waste cooking oils and turn it into high-quality biodiesel.
3. Lower energy consumption: The use of ultrasonication reduces the energy required for mixing and heating the reaction mixture, as well as the amount of catalyst needed, resulting in a more sustainable and cost-effective process.
4. Flexibility and scalability: Hielscher probe-type ultrasonicators and reactors can be used for both small-scale and large-scale production of biodiesel, and can be easily integrated into existing production processes.

In summary this means that the use of a Hielscher ultrasonicators and ultrasound reactors for biodiesel synthesis offer significant benefits in terms of reaction rate, yield, purity, energy consumption, and scalability, making it a profitable technology for the sustainable production of renewable fuels.

Ultrasonic Biodiesel Reactors Reduce Costs and Boost Biodiesel Yield

Excess methanol and catalyst are significant cost factors in biodiesel production. Hielscher ultrasonic reactors use intense cavitational shear for the mixing of methanol with your feedstock. This gives you much smaller methanol droplets resulting in improved methanol and catalyst utilization. Therefore, less excess methanol and less catalyst are required. In addition to that, the cavitation influences the reaction kinetics, leading to faster and more complete transesterification.

Small and Medium Scale Ultrasonic Biodiesel Reactors

For small and medium size biodiesel production systems of up to 9 tons/hour (2900 gallons/hour), Hielscher offers you the UIP500hdT (500 watts), UIP1000hdT (1000 watts), UIP1500hdT (1500 watts) or UIP2000hdT (2000 watts). These four ultrasonic inline reactors are very compact, easy to integrate or retro-fit. They are built for heavy-duty operation in harsh environments. Below you will find recommended reactor setups for a range of production rates.

Full Scale Industrial Ultrasonic Biodiesel Reactors

For industrial biodiesel production plants Hielscher offers the UIP4000hdT (4000 watts), UIP6000hdT (6000 watts), UIP10000hdT (10000 watts) and UIP16000hdT (16000 watts). These ultrasonic homogenizers with inline reactors are designed for the continuous production of biodiesel at high flow rates. All four ultrasonic homogenizers are available in stainless steel cabinets. The vertical installation requires minimal floor space for installation or retrofitting. Below you find recommended setups for typical industrial processing rates.

Inline Ultrasonic Mixing of Oil and Methanol

Ultrasonic mixing reactors replace tank agitators and other dynamic shear mixers. In general, the ultrasonic biodiesel reactors are installed to mix two feed streams: oil and methanol (with catalyst). For this, a crude pre-mix is pumped through the ultrasonic inline reactor, where the ultrasonic cavitation mixes and emulsifies both reagents within 2 to 10 seconds. This is an inline mixing process. When the mix exits the flow cell reactor, the glycerin will separate by gravity in less than 60 minutes. Alternatively, you can feed the sonicated mix into a centrifuge after a few minutes of reaction time. The inline mixing reduces the number and volume of tanks used compared to conventional batch processing. This improves capital utilization.

Ultraääniesteröinti ja transesteröinti voidaan suorittaa eränä tai jatkuvana inline-prosessina. Kaavio näyttää biodieselin (FAME) transesteröinnin ultraääni-inline-prosessin.